18
N-甲基二乙醇胺中的陰離子分析
N-甲基二乙醇胺陰離子報告
Printing time: Wed Sep 29 12:40:04 2010
Injection time: Wed Sep 29 11:37:55 2010
operator: （temporary）, system administrator
分析條件： 儀 器：cic-200 流速：1.0ml/min 量程：1
分離柱：sh-ac 流動相： 碳酸鈉 檢測方式：抑制電導
數(shù)據(jù)僅供參考，不做判定依據(jù)，采用外標法單點校正。
標準品譜圖：
------------------------------------------------
Rank Time Name Quantity Area
------------------------------------------------
1 4.475 COOH 2 1135007
2 5.268 CL 2 2095252
3 7.928 NO3 2 1022979
4 13.107 H2PO4 5 1239713
5 15.043 SO4 3 1908172
6 16.782 OXALIC 2 10855890
7 21.006 S2O3 2 13394106
------------------------------------------------
Total 18 31651119
1#樣品譜圖：
樣品稀釋2500倍過0.22微米濾膜，進樣計算。
File opened: E:\\ÕŽõ÷\\2010\\¶þÒÒ´¼°·\\1# 2500 （20100929 11;37;55）.hw
------------------------------------------------
Rank Time Name Quantity Area
------------------------------------------------
1 4.382 COOH 0 0
2 5.438 CL 36.21 15863
3 7.724 NO3 0 0
4 13.488 H2PO4 1.167e+004 1157335
5 14.568 SO4 0 0
6 16.401 oxalic 0 0
7 20.362 s2o3 0 0
------------------------------------------------
Total 1.171e+004 1173198
3#樣品譜圖：
樣品稀釋1000倍過0.22微米濾膜，進樣計算
------------------------------------------------
Rank Time Name Quantity Area
------------------------------------------------
1 4.604 COOH 86.3 48973
2 5.442 CL 135.6 142021
3 7.982 NO3 0 0
4 13.545 H2PO4 2913 722205
5 15.523 SO4 207.4 131902
6 17.407 OXALIC 8.695 47199
7 21.831 S2O3 22.7 152014
------------------------------------------------
Total 3374 1244314
5#樣品譜圖：（樹脂處理）
樣品稀釋50倍，過陽離子交換樹脂，過0.22微米濾膜，進樣計算
------------------------------------------------
Rank Time Name Quantity Area
------------------------------------------------
1 4.517 COOH 20.49 232579
2 5.323 CL 7.445 155995
3 7.982 NO3 0.9533 9752
4 13.287 H2PO4 3.711 18401
5 15.203 SO4 4.314 54877
6 0.000 OXALIC 0 0
7 0.000 S2O3 0 0
------------------------------------------------
Total 36.91 471604
5#樣品譜圖：
樣品稀釋50倍，過0.22微米濾膜，進樣計算
------------------------------------------------
Rank Time Name Quantity Area
------------------------------------------------
1 4.563 COOH 23.46 266259
2 5.365 CL 1.575 33005
3 7.982 NO3 0 0
4 13.381 H2PO4 2.479 12293
5 15.356 SO4 1.63 20731
6 17.407 OXALIC 0 0
7 21.831 S2O3 0 0
------------------------------------------------
Total 29.14 332288
2#樣品譜圖：（稀釋10倍）
樣品稀釋10倍，過0.22微米濾膜，進樣計算
------------------------------------------------
Rank Time Name Quantity Area
------------------------------------------------
2 4.419 COOH 6.608 3283
3 5.173 CL 640.7 701710
6 7.785 NO3 未計算 99010
7 12.916 H2PO4 未計算 3021572
8 14.780 SO4 212.8 240990
9 16.492 oxalic 6.543 35937
10 20.362 s2o3 0 0
------------------------------------------------
Total 866.7 4102502
4#樣品譜圖：（稀釋10倍）
樣品稀釋10倍，過0.22微米濾膜，進樣計算
------------------------------------------------
Rank Time Name Area% Area
------------------------------------------------
1 4.370 COOH 632.2 46206
2 5.172 CL 1.523e+004 1113462
3 7.787 NO3 1219 89098
4 12.897 H2PO4 2.35e+004 1716794
5 14.791 SO4 7025 513479
6 16.503 oxalic 1457 106517
7 20.769 s2o3 939.7 68681
------------------------------------------------
Total 50003 3654237
6#樣品譜圖：（稀釋10倍）
------------------------------------------------
Rank Time Name Area% Area
------------------------------------------------
1 4.418 COOH 0.09465 1593
2 5.178 CL 68.65 1155244
3 7.803 NO3 5.423 91276
4 12.861 H2PO4 9.984 168035
5 14.774 SO4 15.17 255255
6 16.559 oxalic 0.683 11495
------------------------------------------------
Total 100 1682898
1#樣品磷酸二氫根加標
----------------------------------------------
Rank Time Name Area% Area
----------------------------------------------
1 13.568 H2PO4 41.58 9680883
2 15.421 SO4 1.885 438757
----------------------------------------------
Total 100 23279894